Quantitative chirality synchronization in trifluoroethanol dimers
2006 | journal article. A publication with affiliation to the University of Göttingen.
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Details
- Authors
- Scharge, Tina; Haeber, Thomas; Suhm, Martin A.
- Abstract
- 2,2,2-Trifluoroethanol molecules synchronize their transiently chiral gauche configurations upon dimerization in supersonic jet expansions, while they avoid an energetically competitive heteroconfigurational hydrogen bonded dimer topology predicted by extensive quantum chemical calculations.
- Issue Date
- 2006
- Status
- published
- Publisher
- Royal Soc Chemistry
- Journal
- Physical Chemistry Chemical Physics
- Organization
- Institut für Physikalische Chemie
- ISSN
- 1463-9076
