Internal dynamics in the molecular complex of CF3CN and H2O
2015-07-14 | journal article; research paper
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Details
- Authors
- Lin, Wei; Wu, Anan; Lu, Xin; Tang, Xiao; Obenchain, Daniel A. ; Novick, Stewart E.
- Abstract
- The rotational spectrum of trifluoroacetonitrile-water complex has been studied by pulsed-nozzle, Fourier transform microwave spectroscopy. Both a-type and b-type transitions have been observed. The rotational constants, centrifugal distortion constants, and the (14)N nuclear quadrupole coupling constants have been determined. The complex is T-shaped, with the oxygen atom from the water located 3.135 Å from the carbon atom of CF3 of the trifluoroacetonitrile molecule.
- Issue Date
- 14-July-2015
- Journal
- Physical Chemistry, Chemical Physics
- eISSN
- 1463-9084
- Language
- English