Synthesis and x-ray structure of an isomeric cyclophosphazene complex containing antimony(III)
1993 | journal article. A publication with affiliation to the University of Göttingen.
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Synthesis and x-ray structure of an isomeric cyclophosphazene complex containing antimony(III)
Pandey, S. K.; Hasselbring, R.; Steiner, A.; Stalke, D. & Roesky, H. W. (1993)
Polyhedron, 12(24) pp. 2941-2945. DOI: https://doi.org/10.1016/S0277-5387(00)80043-1
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Details
- Authors
- Pandey, Sushil K.; Hasselbring, Reinhard; Steiner, Alexander; Stalke, Dietmar; Roesky, Herbert W.
- Abstract
- The monosilylated acyclic phosphazene ligand Me3SiNP(NMe2)2NP(NMe2)2 NH2 (3) has been synthesized and characterized. The reaction of 3 with antimony triacetate, Sb(OOCMe3), in refluxing toluene forms a cyclic phosphazene derivative, [N{P(NMe2)2NH}2Sb(OOCMe)2 (4), which is characterized by elemental analyses, mass, IR and NMR spectroscopy and single-crystal X-ray structural analysis. Complex 4 crystallizes in the form of a cis and trans isomeric chain in the solid state.
- Issue Date
- 1993
- Journal
- Polyhedron
- Organization
- Fakultät für Chemie
- File Format
- application/pdf
- Language
- English
