Reaction of triruthenium dodecacarbonyl with nitrobenzene and structure of µ3-phenylnitrene-triruthenium decacarbonyl, [Ru3(CO)10(µ3-NPh)] : Notes. Reaction of triruthenium dodecacarbonyl with nitrobenzene and structure of µ3-phenylnitrene-triruthenium decacarbonyl, [Ru3(CO)10(µ3-NPh) : Notes
1983 | journal article. A publication with affiliation to the University of Göttingen.
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Reaction of triruthenium dodecacarbonyl with nitrobenzene and structure of µ3-phenylnitrene-triruthenium decacarbonyl, [Ru3(CO)10(µ3-NPh)] : Notes. Reaction of triruthenium dodecacarbonyl with nitrobenzene and structure of µ3-phenylnitrene-triruthenium decacarbonyl, [Ru3(CO)10(µ3-NPh) : Notes
Bhaduri, S.; Gopalkrishnan, K. S.; Sheldrick, G. M. ; Clegg, W. & Stalke, D. (1983)
Dalton Transactions, pp. 2339-2341. DOI: https://doi.org/10.1039/DT9830002339
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- Authors
- Bhaduri, Sumit; Gopalkrishnan, Kalpathi S.; Sheldrick, George M. ; Clegg, William; Stalke, Dietmar
- Abstract
- Triruthenium dodecacarbonyl [Ru3(CO)12] reacts with nitrobenzene to give [Ru3(CO)10(NPh)](3) and [Ru3(CO)9(NPh)2](4) in low yields, accompanied by formation of CO2. The solution i.r. spectrum of (3) suggests the presence of triply bridging NPh and CO groups, confirmed by a single-crystal X-ray structure determination; space group P21/n, a= 12.457(1), b= 11.428(1), c= 29.234(2)Å, = 92.38(1)°, Z= 8, and R= 0.036 for 4 817 unique observed reflections. The two independent molecules differ slightly in the relative orientations of the phenyl groups. Mean bond lengths include Ru–Ru 2.746(5), Ru–µ-C 2.172(8), and Ru–µ-N 2.055(5)Å. The i.r. Spectra of complexes (3) and (4) are discussed in terms of a molecular-orbital description of M3(CO)9 moieties.
- Issue Date
- 1983
- Publisher
- Chemical Society
- Journal
- Dalton Transactions
- Organization
- Fakultät für Chemie
- File Format
- application/pdf
- Language
- English