Lithiiertes Di-t- butylfluorsilylmesitylphosphan - vom Phosphan zum Phosphid
1990 | journal article. A publication with affiliation to the University of Göttingen.
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Lithiiertes Di-t- butylfluorsilylmesitylphosphan - vom Phosphan zum Phosphid
Andrianarison, M.; Stalke, D. & Klingebiel, U. (1990)
Journal of Organometallic Chemistry, 381(2) pp. C38-C42. DOI: https://doi.org/10.1016/0022-328X(90)80123-H
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Details
- Authors
- Andrianarison, Mbolatiana; Stalke, Dietmar; Klingebiel, Uwe
- Abstract
- Di-t-butylfluorosilyl-2,4,6-trimethylphenylphosphane reacts with n-C4H9Li in hexane/PMDETA to give the lithium derivative (CMe3)2SiFP(C6H2Me3)Li-(PMDETA), a fluorosilylphosphide which can be interpreted as a contact ion pair. In contrast to this, the free ions [(CMe3)2SiFPC6H2Me3]- and [Li(12 crown 4)2]+ are obtained when the strong Lewis base, 12 crown 4, is used. The crystal structures of both lithium derivatives have been determined and compared.
- Issue Date
- 1990
- Journal
- Journal of Organometallic Chemistry
- Organization
- Fakultät für Chemie
- File Format
- application/pdf
- Language
- English
