Lithium- and dimethylaluminium-di-2-pyridyl-phosphides: the first metal diorganophosphides without a metal–phosphorus bond within a contact ion pair
1993 | journal article. A publication with affiliation to the University of Göttingen.
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Lithium- and dimethylaluminium-di-2-pyridyl-phosphides: the first metal diorganophosphides without a metal–phosphorus bond within a contact ion pair
Steiner, A. & Stalke, D. (1993)
Journal of the Chemical Society. Chemical communications,(5) pp. 444-446. DOI: https://doi.org/10.1039/C39930000444
Documents & Media
Details
- Authors
- Steiner, Alexander; Stalke, Dietmar
- Abstract
- Li{(2-NC5H4)2P}{thf}]2(thf = tetrahydrofuran) and [AlMe2{(2-NC5H4)2P}]3 are obtained in high yield by treating (2-NC5H4)2PH 1, with BunLi and Me3Al, respectively; the X-ray-structure determination confirms that 2 is the first contact ion pair of a lithium diorganophosphide without Li–P contact, which makes the (2-NC5H4)2P– ion a versatile ligand for III/V precursors (already established in 3).
- Issue Date
- 1993
- Journal
- Journal of the Chemical Society. Chemical communications
- Organization
- Fakultät für Chemie
- File Format
- application/pdf
- Language
- English
