Preparation and crystal structure of nonacarbonyl-di-µ-hydrido-µ3-phenylimido-triangulo-triruthenium, [Ru3(µ-H)2(CO)9(µ3-NPh)]
1984 | journal article. A publication with affiliation to the University of Göttingen.
Jump to: Cite & Linked | Documents & Media | Details | Version history
Cite this publication
Preparation and crystal structure of nonacarbonyl-di-µ-hydrido-µ3-phenylimido-triangulo-triruthenium, [Ru3(µ-H)2(CO)9(µ3-NPh)]
Bhaduri, S.; Gopalkrishnan, K. S.; Clegg, W.; Jones, P. G.; Sheldrick, G. M. & Stalke, D. (1984)
Dalton Transactions, pp. 1765-1767. DOI: https://doi.org/10.1039/DT9840001765
Documents & Media
Details
- Authors
- Bhaduri, Sumit; Gopalkrishnan, Kalpathi S.; Clegg, William; Jones, Peter G.; Sheldrick, George M. ; Stalke, Dietmar
- Abstract
- Ru3(CO)10(NPh)](1) reacts with molecular hydrogen to give [Ru3H2(CO)9(NPh)](2), which can be carbonylated to produce [Ru3(CO)12]. A single-crystal X-ray structure determination of (2) confirms the presence of a triply-bridging NPh group and two doubly-bridging hydrogen atoms: space group P21/c, a= 11.697(2), b= 9.265(2), c= 18.589(4)Å, = 100.18(2)°, Z= 4, R= 0.039 for 3 019 unique observed reflections. Mean bond lengths include Ru–Ru 2.805(1)(H-bridged), 2.680(1)(unbridged), Ru–N 2.068(6), Ru–H 1.76(5)Å.
- Issue Date
- 1984
- Journal
- Dalton Transactions
- Organization
- Fakultät für Chemie
- File Format
- application/pdf
- Language
- English
