C–H nitrogenation and oxygenation by ruthenium catalysis
2014 | journal article. A publication with affiliation to the University of Göttingen.
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- Authors
- Thirunavukkarasu, Vedhagiri S.; Kozhushkov, Sergei I.; Ackermann, Lutz
- Abstract
- Remarkable recent progress has been accomplished in direct C–H functionalizations for the formation of C–N and C–O bonds through the use of readily accessible ruthenium catalysts. Particularly, ruthenium(II) complexes allowed for challenging direct C(sp2)–H hydroxylation of arenes. These catalysts set the stage for step-economical C–H functionalization with electron-rich as well as electron-deficient (hetero)arenes and, therefore, provided versatile access to diversely decorated phenols. While a number of synthetically useful protocols for ruthenium-catalyzed C(sp3)–H bond nitrogenation have been elaborated, the analogous transformations of more stable C(sp2)–H bonds were very recently achieved.
- Issue Date
- 2014
- Status
- published
- Publisher
- Royal Soc Chemistry
- Journal
- Chemical Communications
- Organization
- Fakultät für Chemie
- ISSN
- 1364-548X; 1359-7345
- Language
- English
- Notes
- This publication is with permission of the rights owner freely accessible due to an Alliance licence and a national licence (funded by the DFG, German Research Foundation) respectively.