Thiazolium carbene catalysts for the fixation of CO2 onto amines

2016 | journal article. A publication with affiliation to the University of Göttingen.

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​Thiazolium carbene catalysts for the fixation of CO2 onto amines​
Das, S.; Bobbink, F. D.; Bulut, S.; Soudani, M. & Dyson, P. J.​ (2016) 
Chemical Communications52(12) pp. 2497​-2500​.​ DOI: https://doi.org/10.1039/C5CC08741D 

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Authors
Das, Shoubhik; Bobbink, Felix D.; Bulut, Safak; Soudani, Mylène; Dyson, Paul J.
Abstract
The catalytic N-formylation and N-methylation of amines using CO2 as the carbon source represents a facile and sustainable approach for the synthesis of pharmaceuticals and natural products. Herein, we describe highly effective and inexpensive thiazolium carbenebased catalysts derived from vitamin B1 for the N-formylation and N-methylation of amines, using polymethylhydrosiloxane (PMHS) as a reducing agent, which operate under ambient conditions.
Issue Date
2016
Status
published
Publisher
Royal Soc Chemistry
Journal
Chemical Communications 
Organization
Fakultät für Chemie 
ISSN
1364-548X; 1359-7345
Language
English

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