Isolation, structure and MO calculational investigations of a highly stable, hydrogen-bonded primary amine–phosphine oxide adduct, 2-aminobenzothiazole–HMPA, C6H4SC(N)NH2OP(NMe2)3; a possible model to explain the carcinogenicity of HMPA (HMPA = hexamethylphosphoramide)
1992 | journal article. A publication with affiliation to the University of Göttingen.
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Isolation, structure and MO calculational investigations of a highly stable, hydrogen-bonded primary amine–phosphine oxide adduct, 2-aminobenzothiazole–HMPA, C6H4SC(N)NH2OP(NMe2)3; a possible model to explain the carcinogenicity of HMPA (HMPA = hexamethylphosphoramide)
Armstrong, D. R.; Bennett, S.; Davidson, M. G.; Snaith, R.; Stalke, D. & Wright, D. S. (1992)
Journal of the Chemical Society. Chemical communications,(3) pp. 262-264. DOI: https://doi.org/10.1039/C39920000262
Documents & Media
Details
- Authors
- Armstrong, David R.; Bennett, Susan; Davidson, Matthew G.; Snaith, Ronald; Stalke, Dietmar ; Wright, Dominic S.
- Abstract
- Colourless needles of the 1 : 1 primary amine-phosphine oxide adduct CsH4SC(=N)NH2.0=P(NMe2)a3r e obtained in high yield simply by chilling a toluene solution of the two components; the solid-state structure of the highly stable adduct (which can be prepared in water, and which sublimes easily) consists essentially of dimers held by (amine) N-H...O and (amine)N-H...(heterocyclic) N hydrogen bonds.
- Issue Date
- 1992
- Journal
- Journal of the Chemical Society. Chemical communications
- Organization
- Fakultät für Chemie
- File Format
- application/pdf
- Language
- English
