The observation of a Pb–Li bond; synthesis, structure and model molecular orbital (MO) calculations on the monomeric Ph3Pb–Li·(pmdeta) complex [pmdeta =(Me2NCH2CH2)2NMe]
1992 | journal article. A publication with affiliation to the University of Göttingen.
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The observation of a Pb–Li bond; synthesis, structure and model molecular orbital (MO) calculations on the monomeric Ph3Pb–Li·(pmdeta) complex [pmdeta =(Me2NCH2CH2)2NMe]
Armstrong, D. R.; Davidson, M. G.; Moncrieff, D.; Stalke, D. & Wright, D. S. (1992)
Journal of the Chemical Society. Chemical communications,(19) pp. 1413-1415. DOI: https://doi.org/10.1039/C39920001413
Documents & Media
Details
- Authors
- Armstrong, David R.; Davidson, Matthew G.; Moncrieff, David; Stalke, Dietmar ; Wright, Dominic S.
- Abstract
- The title compound has been synthesised by the cleavage reaction of Ph3Pb–PbPh3 with BunLi and has been shown to have a monomeric Pb–Li bonded structure in the solid state; ab initio calculations have been used to probe the nature of the early main group metal/heavy p block metal bonding involved.
- Issue Date
- 1992
- Journal
- Journal of the Chemical Society. Chemical communications
- Organization
- Fakultät für Chemie
- File Format
- application/pdf
- Language
- English
