Hydridoorganostannylene Coordination: Group 4 Metallocene Dichloride Reduction in Reaction with Organodihydridostannate Anions
2019 | journal article. A publication with affiliation to the University of Göttingen.
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Hydridoorganostannylene Coordination: Group 4 Metallocene Dichloride Reduction in Reaction with Organodihydridostannate Anions
Maudrich, J.; Widemann, M.; Diab, F.; Kern, R. H.; Sirsch, P.; Sindlinger, C. P. & Schubert, H. et al. (2019)
Chemistry: a European Journal, 25(25) pp. 1-8. DOI: https://doi.org/10.1002/chem.201903652
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Details
- Authors
- Maudrich, Jakob‐Jonathan; Widemann, Max; Diab, Fatima; Kern, Ralf H.; Sirsch, Peter; Sindlinger, Christian P.; Schubert, Hartmut; Wesemann, Lars
- Abstract
- Organodihydridoelement anions of germanium and tin were reacted with metallocene dichlorides of Group 4 metals Ti, Zr and Hf. The germate anion [Ar GeH2 ]- reacts with hafnocene dichloride under formation of the substitution product [Cp2 Hf(GeH2 Ar )2 ]. Reaction of the organodihydridostannate with metallocene dichlorides affords the reduction products [Cp2 M(SnHAr )2 ] (M=Ti, Zr, Hf). Abstraction of a hydride substituent from the titanium bis(hydridoorganostannylene) complex results in formation of cation [Cp2 M(SnAr )(SnHAr )]+ exhibiting a short Ti-Sn interaction. (Ar =2,6-Trip2 C6 H3 , Trip=2,4,6-triisopropylphenyl).
- Issue Date
- 2019
- Journal
- Chemistry: a European Journal
- Organization
- Fakultät für Chemie
- ISSN
- 0947-6539
- eISSN
- 1521-3765
- ISSN
- 1521-3765; 0947-6539
- eISSN
- 1521-3765
- Language
- English
