Prof. Dr. Herbert W. Roesky

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  • 2022 | Journal Article | 
    ​ ​Excellent yield of a variety of silicon-boron radicals and their reactivity​
    Nazish, M.; Ding, Y.; Legendre, C. M.; Kumar, A.; Graw, N. ; Schwederski, B. & Herbst-Irmer, R.  et al.​ (2022) 
    Dalton Transactions, 51(29) pp. 11040​-11047​.​ DOI: https://doi.org/10.1039/D2DT01318E 
    ​Details  DOI 
  • 2022 | Journal Article
    ​ ​Insertion Reaction of Me3SiN3 with Bis(germylene)​
    Ding, Y.; Sarkar, S. K.; Nazish, M.; Ruth, P. N.; Herbst-Irmer, R. ; Muhammed, S. & Parameswaran, P. et al.​ (2022) 
    Inorganic Chemistry, art. acs.inorgchem.2c02252​.​ DOI: https://doi.org/10.1021/acs.inorgchem.2c02252 
    ​Details  DOI 
  • 2021 | Journal Article
    ​ ​Pentamethyl- and 1,2,4-tri( tert -butyl)cyclopentadienyl containing p-block complexes – differences and similarities​
    Ding, Y.; Ruth, P. N.; Herbst-Irmer, R. ; Stalke, D. ; Yang, Z. & Roesky, H. W. ​ (2021) 
    Dalton Transactions, 50(6) pp. 2067​-2074​.​ DOI: https://doi.org/10.1039/d0dt04412a 
    ​Details  DOI 
  • 2021 | Journal Article
    ​ ​Donor-Stabilized Antimony(I) and Bismuth(I) Ions: Heavier Valence Isoelectronic Analogues of Carbones​
    Siddiqui, M. M.; Sarkar, S. K.; Nazish, M.; Morganti, M.; Köhler, C.; Cai, J. & Zhao, L. et al.​ (2021) 
    Journal of the American Chemical Society, 143(3) pp. 1301​-1306​.​ DOI: https://doi.org/10.1021/jacs.0c12084 
    ​Details  DOI 
  • 2021 | Journal Article | 
    ​ ​MesPX2/IsPX2 as Precursors for the Preparation of Phosphasilenes​
    Liu, Y.; Keil, H.; Zhong, M.; Li, J.; Yang, Z.; Herbst‐Irmer, R.   & Stalke, D.  et al.​ (2021) 
    European Journal of Inorganic Chemistry, 2021(7) pp. 639​-643​.​ DOI: https://doi.org/10.1002/ejic.202000966 
    ​Details  DOI 
  • 2020 | Journal Article
    ​ ​Amidinate based indium( iii ) monohalides and β-diketiminate stabilized In( ii )–In( ii ) bond: synthesis, crystal structure, and computational study​
    Banerjee, S.; Dutta, S.; Sarkar, S. K.; Graw, N. ; Herbst-Irmer, R. ; Koley, D. & Stalke, D.  et al.​ (2020) 
    Dalton Transactions, 49(40) pp. 14231​-14236​.​ DOI: https://doi.org/10.1039/d0dt03161e 
    ​Details  DOI 
  • 2020 | Journal Article
    ​ ​Cyclic (Alkyl)(Amino)Carbene-Stabilized Aluminum and Gallium Radicals Based on Amidinate Scaffolds​
    Siddiqui, M. M.; Banerjee, S.; Bose, S.; Sarkar, S. K.; Gupta, S. K.; Kretsch, J. & Graw, N.  et al.​ (2020) 
    Inorganic Chemistry, 59(16) pp. 11253​-11258​.​ DOI: https://doi.org/10.1021/acs.inorgchem.0c01913 
    ​Details  DOI 
  • 2020 | Journal Article
    ​ ​A Neutral Three‐Membered 2π Aromatic Disilaborirane and the Unique Conversion into a Four‐Membered BSi 2 N‐Ring​
    Sarkar, S. K.; Chaliha, R.; Siddiqui, M. M.; Banerjee, S.; Münch, A.; Herbst‐Irmer, R.   & Stalke, D.  et al.​ (2020) 
    Angewandte Chemie International Edition, 59(51) pp. 23015​-23019​.​ DOI: https://doi.org/10.1002/anie.202009638 
    ​Details  DOI 
  • 2020 | Journal Article
    ​ ​Reactions of Amidinate-Supported Silylene with Organoboron Dihalides​
    Li, J.; Liu, Y.; Kundu, S.; Keil, H.; Zhu, H.; Herbst-Irmer, R.   & Stalke, D.  et al.​ (2020) 
    Inorganic Chemistry, 59(12) pp. 7910​-7914​.​ DOI: https://doi.org/10.1021/acs.inorgchem.0c00843 
    ​Details  DOI 
  • 2020 | Journal Article | 
    ​ ​Phosphorus Silicon Compounds from the Reduction of MesP(H)SiCl2Ph/Carbene with and without Metal​
    Liu, Y.; Keil, H.; Yang, Z.; Herbst-Irmer, R. ; Roesky, H. W.   & Stalke, D. ​ (2020) 
    European Journal of Inorganic Chemistry, 2020(23) pp. 2273​-2278​.​ DOI: https://doi.org/10.1002/ejic.202000294 
    ​Details  DOI 
  • 2019 | Journal Article
    ​ ​Isolation of Transient Acyclic Germanium(I) Radicals Stabilized by Cyclic Alkyl(amino) Carbenes​
    Siddiqui, M. M.; Sarkar, S. K.; Sinhababu, S.; Ruth, P. N.; Herbst-Irmer, R. ; Stalke, D.   & Ghosh, M. et al.​ (2019) 
    Journal of the American Chemical Society, 141(5) pp. 1908​-1912​.​ DOI: https://doi.org/10.1021/jacs.8b13434 
    ​Details  DOI 
  • 2019 | Journal Article
    ​ ​Cyclic Alkyl(amino) Carbene-Stabilized Monoradicals of Organosilicon(IV) Compounds with Small Substituents​
    Li, W.; Kundu, S.; Köhler, C.; Li, J.; Dutta, S.; Yang, Z. & Stalke, D.  et al.​ (2019) 
    Organometallics, 38(9) pp. 1939​-1945​.​ DOI: https://doi.org/10.1021/acs.organomet.9b00041 
    ​Details  DOI 
  • 2019 | Journal Article
    ​ ​HAlCl 2 and H 2 AlCl as Precursors for the Preparation of Compounds with Four- and Five-Coordinate Aluminum​
    Zhong, M.; Liu, Y.; Kundu, S.; Graw, N. ; Li, J.; Yang, Z. & Herbst-Irmer, R.  et al.​ (2019) 
    Inorganic Chemistry, 58(16) pp. 10625​-10628​.​ DOI: https://doi.org/10.1021/acs.inorgchem.9b02001 
    ​Details  DOI 
  • 2019 | Journal Article | 
    ​ ​(PhC(N t Bu) 2 Al) 2 (SiH 2 ) 4 six-membered heterocycle: comparable in structure to cyclohexane​
    Li, J.; Zhong, M.; Keil, H.; Zhu, H.; Herbst-Irmer, R. ; Stalke, D.   & De, S. et al.​ (2019) 
    Chemical Communications, 55(16) pp. 2360​-2363​.​ DOI: https://doi.org/10.1039/C8CC10124H 
    ​Details  DOI 
  • 2019 | Journal Article | 
    ​ ​Treatment of Silylene–Phosphinidene with Chalcogens Resulted Exclusively in the Formation of Silicon‐Bonded Chalcogens​
    Sinhababu, S.; Siddiqui, M. M.; Sarkar, S. K.; Münch, A.; Herbst‐Irmer, R. ; George, A. & Parameswaran, P. et al.​ (2019) 
    Chemistry – A European Journal, 25(49) pp. 11422​-11426​.​ DOI: https://doi.org/10.1002/chem.201902661 
    ​Details  DOI 
  • 2018 | Journal Article
    ​ ​Synthesis of Cyclic Alkyl(amino) Carbene Stabilized Silylenes with Small N‐Donating Substituents​
    Li, W.; Köhler, C.; Yang, Z.; Stalke, D. ; Herbst‐Irmer, R.   & Roesky, H. W. ​ (2018) 
    Chemistry – A European Journal,.​ DOI: https://doi.org/10.1002/chem.201805267 
    ​Details  DOI 
  • 2018 | Journal Article
    ​ ​A Route to Aluminumdiisocyanate and -diisothiocyanate from an Al(I) Precursor​
    Sinhababu, S.; Kundu, S.; Paesch, A. N.; Herbst-Irmer, R. ; Stalke, D.   & Roesky, H. W. ​ (2018) 
    European Journal of Inorganic Chemistry, 2018(20-21) pp. 2237​-2240​.​ DOI: https://doi.org/10.1002/ejic.201701347 
    ​Details  DOI 
  • 2018 | Journal Article
    ​ ​A Dicobalt Coordination Complex with a Short Cobalt-Cobalt Distance​
    Kumar, J.; Gorantla, N. V. T. S. M.; Roy, S.; Paesch, A. N.; Herbst-Irmer, R. ; Stalke, D.   & Anusha, C. et al.​ (2018) 
    ChemistrySelect, 3(28) pp. 8221​-8228​.​ DOI: https://doi.org/10.1002/slct.201801172 
    ​Details  DOI 
  • 2018 | Journal Article
    ​ ​A Route to Base Coordinate Silicon Difluoride and the Silicon Trifluoride Radical​
    Sinhababu, S.; Kundu, S.; Paesch, A. N.; Herbst-Irmer, R. ; Stalke, D. ; Fernández, I. & Frenking, G. et al.​ (2018) 
    Chemistry - A European Journal, 24(6) pp. 1264​-1268​.​ DOI: https://doi.org/10.1002/chem.201705773 
    ​Details  DOI 
  • 2018 | Journal Article
    ​ ​Silanylidene and Germanylidene Anions: Valence‐Isoelectronic Species to the Well‐Studied Phosphinidene​
    Siddiqui, M. M.; Sinhababu, S.; Dutta, S.; Kundu, S.; Ruth, P. N.; Münch, A. & Herbst‐Irmer, R.  et al.​ (2018) 
    Angewandte Chemie International Edition, 57(36) pp. 11776​-11780​.​ DOI: https://doi.org/10.1002/anie.201805936 
    ​Details  DOI 
  • 2017 | Journal Article
    ​ ​Two Structurally Characterized Conformational Isomers with Different C−P Bonds​
    Roy, S.; Mondal, K. C.; Kundu, S.; Li, B.; Schürmann, C. J.; Dutta, S. & Koley, D. et al.​ (2017) 
    Chemistry - A European Journal, 23(50) pp. 12153​-12157​.​ DOI: https://doi.org/10.1002/chem.201702870 
    ​Details  DOI 
  • 2015 | Journal Article
    ​ ​Carbene-Dichlorosilylene Stabilized Phosphinidenes Exhibiting Strong Intramolecular Charge Transfer Transition​
    Roy, S.; Stollberg, P.; Herbst-Irmer, R. ; Stalke, D. ; Andrada, D. M.; Frenking, G. & Roesky, H. W. ​ (2015) 
    Journal of the American Chemical Society, 137(1) pp. 150​-153​.​ DOI: https://doi.org/10.1021/ja512089e 
    ​Details  DOI  PMID  PMC  WoS 
  • 2013 | Journal Article
    ​ ​Conversion of a Singlet Silylene to a stable Biradical​
    Mondal, K. C.; Roesky, H. W. ; Schwarzer, M. C.; Frenking, G.; Tkach, I.; Wolf, H. & Kratzert, D. et al.​ (2013) 
    Angewandte Chemie International Edition, 52(6) pp. 1801​-1805​.​ DOI: https://doi.org/10.1002/anie.201204487 
    ​Details  DOI  PMID  PMC  WoS 
  • 2013 | Journal Article
    ​ ​Reaction of N-Heterocyclic Silylenes with Thioketone: Formation of SiliconSulfur Three (Si-C-S)- and Five (Si-C-C-C-S)-Membered Ring Systems​
    Azhakar, R.; Ghadwal, R. S. ; Roesky, H. W. ; Mata, R. A. ; Wolf, H.; Herbst-Irmer, R.   & Stalke, D. ​ (2013) 
    Chemistry: a European Journal, 19(11) pp. 3715​-3720​.​ DOI: https://doi.org/10.1002/chem.201203242 
    ​Details  DOI  PMID  PMC  WoS 
  • 2012 | Journal Article
    ​ ​Monomeric Sn(II) and Ge(II) hydrides supported by a tridentate pincer-based ligand​
    Khan, S.; Samuel, P. P. ; Michel, R.; Dieterich, J. M.; Mata, R. A. ; Demers, J.-P. & Lange, A.  et al.​ (2012) 
    Chemical Communications, 48(40) pp. 4890​-4892​.​ DOI: https://doi.org/10.1039/c2cc31214j 
    ​Details  DOI  PMID  PMC  WoS 
  • 2011 | Journal Article
    ​ ​Preparation of RSn(I)-Sn(I)R with Two Unsymmetrically Coordinated Sn(I) Atoms and Subsequent Gentle Activation of P-4​
    Khan, S.; Michel, R.; Dieterich, J. M.; Mata, R. A. ; Roesky, H. W. ; Demers, J.-P. & Lange, A.  et al.​ (2011) 
    Journal of the American Chemical Society, 133(44) pp. 17889​-17894​.​ DOI: https://doi.org/10.1021/ja207538g 
    ​Details  DOI  PMID  PMC  WoS 
  • 2011 | Journal Article
    ​ ​A Stable Cation of a CSi3P Five-Membered Ring with a Weakly Coordinating Chloride Anion​
    Sen, S. S.; Hey, J.; Eckhardt, M.; Herbst-Irmer, R. ; Maedl, E.; Mata, R. A.   & Roesky, H. W.  et al.​ (2011) 
    Angewandte Chemie International Edition, 50(52) pp. 12510​-12513​.​ DOI: https://doi.org/10.1002/anie.201104146 
    ​Details  DOI  PMID  PMC  WoS 
  • 1993 | Journal Article | 
    ​ ​Metallation of the acyclic phosphazene ligand HN[P(NMe2)2NSiMe3]2. Synthesis and crystal structure of {NaN[P(NMe2)2NSiMe3]2}2, {KN[P(NMe2)2NSiMe3]2} and Ca{N[P(NMe2)2NSiMe3]2}2​
    Hasselbring, R.; Pandey, S. K.; Roesky, H. W. ; Stalke, D.   & Steiner, A.​ (1993) 
    Dalton Transactions,(22) pp. 3447​-3451​.​ DOI: https://doi.org/10.1039/DT9930003447 
    ​Details  DOI 
  • 1992 | Journal Article | 
    ​ ​Synthese und Struktur von CpAlCl2-Verbindungen mit sterisch anspruchsvollen Substituenten (Cp = Me5C5, EtMe4C5)​
    Koch, H.-J.; Schulz, S.; Roesky, H. W. ; Noltemeyer, M.; Schmidt, H.-G.; Heine, A. & Herbst-Irmer, R.  et al.​ (1992) 
    Chemische Berichte, 125(5) pp. 1107​-1109​.​ DOI: https://doi.org/10.1002/cber.19921250520 
    ​Details  DOI 
  • 1991 | Journal Article | 
    ​ ​Four- and eight-membered cyclic phosphazene derivatives of zirconium, titanium and vanadium. Crystal structures of the complexes [ZrCl3(Me3SiNPPh2NSiMe3)]·MeCN and [{TiCl2(OPPh2N)}2]·4MeCN​
    Witt, M.; Stalke, D. ; Henkel, T.; Roesky, H. W.   & Sheldrick, G. M. ​ (1991) 
    Dalton Transactions, pp. 663​.​ DOI: https://doi.org/10.1039/DT9910000663 
    ​Details  DOI 
  • 1991 | Journal Article | 
    ​ ​Darstellung und Struktur von Thallium(I)-2,4,6-tris(trifluormethyl)thiophenolat, einer Verbindung mit faltblattartig-polymerem Aufbau​
    Labahn, D.; Pohl, E.; Herbst-Irmer, R. ; Stalke, D. ; Roesky, H. W.   & Sheldrick, G. M. ​ (1991) 
    Chemische Berichte, 124(5) pp. 1127​-1129​.​ DOI: https://doi.org/10.1002/cber.19911240522 
    ​Details  DOI 
  • 1989 | Journal Article | 
    ​ ​Synthesis and crystal structures of three four-membered ring compounds containing PN2Ti skeletons​
    Witt, M.; Roesky, H. W. ; Stalke, D. ; Pauer, F.; Henkel, T. & Sheldrick, G. M. ​ (1989) 
    Dalton Transactions,(11) pp. 2173​-2177​.​ DOI: https://doi.org/10.1039/DT9890002173 
    ​Details  DOI 
  • 1989 | Journal Article | 
    ​ ​A volatile cyclic metallaphosphazene; preparation and X-ray structure of [(CF3)2PN]2NVCl2​
    Roesky, H. W. ; Olms, P.; Witt, M.; Keller, K.; Stalke, D. ; Henkel, T. & Sheldrick, G. M. ​ (1989) 
    Journal of the Chemical Society. Chemical communications,(6) pp. 366​-367​.​ DOI: https://doi.org/10.1039/C39890000366 
    ​Details  DOI 

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