Quantum effects in the capture of charged particles by dipolar polarizable symmetric top molecules. I. General axially nonadiabatic channel treatment
2013 | journal article. A publication of Göttingen
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Quantum effects in the capture of charged particles by dipolar polarizable symmetric top molecules. I. General axially nonadiabatic channel treatment
Auzinsh, M.; Dashevskaya, E. I.; Litvin, I.; Nikitin, E. E. & Troe, J. (2013)
The Journal of Chemical Physics, 139(8) art. 084311. DOI: https://doi.org/10.1063/1.4819062
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Details
- Authors
- Auzinsh, M.; Dashevskaya, Elena I.; Litvin, Ilya; Nikitin, E. E.; Troe, Juergen
- Abstract
- The rate coefficients for capture of charged particles by dipolar polarizable symmetric top molecules in the quantum collision regime are calculated within an axially nonadiabatic channel approach. It uses the adiabatic approximation with respect to rotational transitions of the target within first-order charge-dipole interaction and takes into account the gyroscopic effect that decouples the intrinsic angular momentum from the collision axis. The results are valid for a wide range of collision energies (from single-wave capture to the classical limit) and dipole moments (from the Vogt-Wannier and fly-wheel to the adiabatic channel limit). (C) 2013 AIP Publishing LLC.
- Issue Date
- 2013
- Status
- published
- Publisher
- Amer Inst Physics
- Journal
- The Journal of Chemical Physics
- ISSN
- 0021-9606
- Sponsor
- EOARD [FA 8655-11-1-3077]