Chirality-dependent balance between hydrogen bonding and London dispersion in isolated (+/-)-1-indanol clusters
2013 | journal article. A publication with affiliation to the University of Göttingen.
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Altnoeder, Jonas, Aude Bouchet, Juhyon J. Lee, Katharina E. Otto, Martin A. Suhm, and Anne Zehnacker-Rentien. "Chirality-dependent balance between hydrogen bonding and London dispersion in isolated (+/-)-1-indanol clusters." Physical Chemistry Chemical Physics 15, no. 25 (2013): 10167-10180. https://doi.org/10.1039/c3cp50708d.
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Details
- Authors
- Altnoeder, Jonas; Bouchet, Aude; Lee, Juhyon J.; Otto, Katharina E.; Suhm, Martin A. ; Zehnacker-Rentien, Anne
- Abstract
- The aggregation behavior of racemic and enantiopure 1-indanol has been studied by FTIR spectroscopy, resonant ion dip IR spectroscopy, and spontaneous Raman scattering in supersonic jets. This triple experimental approach, augmented by homology to related molecular fragments and dispersion-corrected DFT predictions, allows disentangling the complex spectroscopic signature in the OH stretch range. Evidence for chirality-sensitive aggregation via isolated OH center dot center dot center dot pi bonds in competition with cooperative center dot center dot center dot OH center dot center dot center dot OH center dot center dot center dot pi patterns is collected. An accurate description of London dispersion forces provides the key to its explanation.
- Issue Date
- 2013
- Status
- published
- Publisher
- Royal Soc Chemistry
- Journal
- Physical Chemistry Chemical Physics
- Organization
- Institut für Physikalische Chemie
- ISSN
- 1463-9084; 1463-9076
