Microscopic Roots of Alcohol-Ketone Demixing: Infrared Spectroscopy of Methanol-Acetone Clusters
2015 | journal article. A publication of Göttingen
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Microscopic Roots of Alcohol-Ketone Demixing: Infrared Spectroscopy of Methanol-Acetone Clusters
Kollipost, F.; Domanskaya, A. V. & Suhm, M. A. (2015)
The Journal of Physical Chemistry. A, Molecules, spectroscopy, kinetics, environment & general theory, 119(11) pp. 2225-2232. DOI: https://doi.org/10.1021/jp503999b
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Details
- Authors
- Kollipost, Franz; Domanskaya, Alexandra V.; Suhm, Martin A.
- Abstract
- Infrared spectra Of isolated methanol acetone clusters up to tetramers are experimentally characterized for the flint time. They show evidence for a nanometer-scale demixing trend of the cold species. In combination with quantum calculations, the mutual repulsion is demonstrated to start beyond three molecular, units, whereas individual molecules still prefer to form a mixed complex.
- Issue Date
- 2015
- Status
- published
- Publisher
- Amer Chemical Soc
- Journal
- The Journal of Physical Chemistry. A, Molecules, spectroscopy, kinetics, environment & general theory
- Organization
- Institut für Physikalische Chemie
- ISSN
- 1089-5639
- Sponsor
- DFG (Deutsche Forschungsgemeinschaft) [Su 121/4]
