Ammonolysis of M-Cl bonds of organozirconium(IV) and titanium(III) chlorides in a liquid ammonia/toluene two phase system

2002 | journal article. A publication of Göttingen

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​Ammonolysis of M-Cl bonds of organozirconium(IV) and titanium(III) chlorides in a liquid ammonia/toluene two phase system​
Bai, G. C.; Roesky, H. W.   & Mueller, P.​ (2002) 
BULLETIN OF THE POLISH ACADEMY OF SCIENCES-CHEMISTRY50(1) pp. 1​-10​.​

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Authors
Bai, G. C.; Roesky, H. W. ; Mueller, P.
Abstract
Treatment of (MeC5H4)(2)ZrCl2 with K (Na) or NaNH2 in liquid ammonia/toluene at -78degreesC led to the pentanuclear zirconium cluster [{(MeC5H4)Zr}(5)(mu(5) - N)(mu(3) - NH)(4)(mu - NH2)(4)] (1) and the alkali metal aggregate [(MeC5H4)M](n) (M = K (2) or Na). Reaction of Cp-2 TiCl with NaNH2 in liquid ammonia/toluene at -78degreesC yielded Cp-2 TiNH2 (3).
Issue Date
2002
Journal
BULLETIN OF THE POLISH ACADEMY OF SCIENCES-CHEMISTRY 
ISSN
0239-7285

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