Solution structures of alkali metal cyclopentadienides in THF estimated by ECC-DOSY NMR-spectroscopy (incl. software).

Solution structures of alkali metal cyclopentadienides in THF estimated by ECC-DOSY NMR-spectroscopy (incl. software).
Bachmann, S.; Gernert, B. & Stalke, D. (2016) 
Chemical communications (Cambridge, England),.​

Authors
Bachmann, Sebastian; Gernert, Björn; Stalke, Dietmar
Issue Date
12-October-2016
Type
Journal Article
Abstract
In this paper we present the aggregational motifs of the widely used alkali-metal cyclopentadienides (CpLi, CpNa, CpK, CpRb, CpCs) in THF-d8 solution estimated by ECC-DOSY NMR spectroscopy. They form monomeric contact ion pairs (CIPs) in THF-d8 solution, whereas in NH3 solvent-separated ion pairs (SSIPs) are observed. The applicability of ECC-DOSY is further advanced by introducing ECC-MW estimation software.
Journal
Chemical communications (Cambridge, England) 
ISSN
1364-548X
Extent
4
Language
English
Publication of Göttingen University
Yes
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