Solution structures of alkali metal cyclopentadienides in THF estimated by ECC-DOSY NMR-spectroscopy (incl. software).
2016-10-12 | journal article. A publication with affiliation to the University of Göttingen.
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Bachmann, Sebastian, Björn Gernert, and Dietmar Stalke. "Solution structures of alkali metal cyclopentadienides in THF estimated by ECC-DOSY NMR-spectroscopy (incl. software).." Chemical communications (Cambridge, England) (2016): . https://doi.org/10.1039/c6cc07273a.
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Details
- Authors
- Bachmann, Sebastian; Gernert, Björn; Stalke, Dietmar
- Abstract
- In this paper we present the aggregational motifs of the widely used alkali-metal cyclopentadienides (CpLi, CpNa, CpK, CpRb, CpCs) in THF-d8 solution estimated by ECC-DOSY NMR spectroscopy. They form monomeric contact ion pairs (CIPs) in THF-d8 solution, whereas in NH3 solvent-separated ion pairs (SSIPs) are observed. The applicability of ECC-DOSY is further advanced by introducing ECC-MW estimation software.
- Issue Date
- 12-October-2016
- Journal
- Chemical communications (Cambridge, England)
- ISSN
- 1364-548X
- Extent
- 4
- Language
- English
