Darstellung und Struktur von Thallium(I)-2,4,6-tris(trifluormethyl)thiophenolat, einer Verbindung mit faltblattartig-polymerem Aufbau
1991 | journal article. A publication of Göttingen
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Darstellung und Struktur von Thallium(I)-2,4,6-tris(trifluormethyl)thiophenolat, einer Verbindung mit faltblattartig-polymerem Aufbau
Labahn, D.; Pohl, E.; Herbst-Irmer, R. ; Stalke, D. ; Roesky, H. W. & Sheldrick, G. M. (1991)
Chemische Berichte, 124(5) pp. 1127-1129. DOI: https://doi.org/10.1002/cber.19911240522
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Details
- Title Variant(s)
- Preparation and Structure of Thallium(I) 2,4,6-Tris(trifluoromethyl thiophenolate, a Compound with a Folded Polymeric Structure
- Authors
- Labahn, Dieter; Pohl, Ehmke; Herbst-Irmer, Regine ; Stalke, Dietmar ; Roesky, Herbert W. ; Sheldrick, George M.
- Abstract
- The title compound, thallium(I) 2,4,6-tris(trifluoromethyl)thiophenolate (1) has been prepared by using either TlOEt and (CF3)3C6H2p. or Tl2CO3 and (CF3)3C6H2SNa. A single X-ray structural analysis shows a folded polymeric structure for 1; the crystal lattice incorporates half of a 1,4-dioxane molecule per Tl atom. This compound has a surprisingly high kinetic stability compared to known thallium(I) thiolates.
- Issue Date
- 1991
- Journal
- Chemische Berichte
- Language
- German
