Insertion of zinc into the cyclophosphazene skeleton: synthesis and structure of six-membered-ring complexes of zinc
1993 | journal article. A publication with affiliation to the University of Göttingen.
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Insertion of zinc into the cyclophosphazene skeleton: synthesis and structure of six-membered-ring complexes of zinc
Pandey, S. K.; Steiner, A.; Roesky, H. W. & Stalke, D. (1993)
Inorganic Chemistry, 32(24) pp. 5444-5446. DOI: https://doi.org/10.1021/ic00076a007
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Details
- Authors
- Pandey, Sushil K.; Steiner, Alexander; Roesky, Herbert W.; Stalke, Dietmar
- Abstract
- Cyclozincaphosphazenes have been synthesized by the reaction of the bis-silylated ligand HN[P(NMe2)2NSiMe3]2 (1) with ZnR2 (2) (R = N(SiMe&, Me, Et). These complexes have been characterized by IR, NMR, and mass spectroscopy and by X-ray crystal structural analysis. X-ray analysis of [N(P(NMe2)2NSiMe3]2ZnN(SiMe3)2(]3 ) revealed that it crystallizes as a monomer in the solid state.
- Issue Date
- 1993
- Journal
- Inorganic Chemistry
- Language
- English