Insertion of zinc into the cyclophosphazene skeleton: synthesis and structure of six-membered-ring complexes of zinc
1993 | journal article. A publication with affiliation to the University of Göttingen.
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Pandey SK, Steiner A, Roesky HW, Stalke D. Insertion of zinc into the cyclophosphazene skeleton: synthesis and structure of six-membered-ring complexes of zinc. Inorganic Chemistry. 1993;32(24):5444-5446. doi:10.1021/ic00076a007.
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- Authors
- Pandey, Sushil K.; Steiner, Alexander; Roesky, Herbert W.; Stalke, Dietmar
- Abstract
- Cyclozincaphosphazenes have been synthesized by the reaction of the bis-silylated ligand HN[P(NMe2)2NSiMe3]2 (1) with ZnR2 (2) (R = N(SiMe&, Me, Et). These complexes have been characterized by IR, NMR, and mass spectroscopy and by X-ray crystal structural analysis. X-ray analysis of [N(P(NMe2)2NSiMe3]2ZnN(SiMe3)2(]3 ) revealed that it crystallizes as a monomer in the solid state.
- Issue Date
- 1993
- Journal
- Inorganic Chemistry
- Language
- English