Deoxygenating Reduction of CO2 by [Cp*Al]4 to Form a (Al3O2C)2 Cluster Featuring Two Ketene Moieties
2022 | journal article. A publication with affiliation to the University of Göttingen.
Jump to: Cite & Linked | Documents & Media | Details | Version history
Cite this publication
Deoxygenating Reduction of CO2 by [Cp*Al]4 to Form a (Al3O2C)2 Cluster Featuring Two Ketene Moieties
Wang, B.; Zhuang, Y.; Tu, D.; Shen, L.; Zhang, Z.-F.; Su, M.-D. & Li, Y. et al. (2022)
Inorganic Chemistry, 61(37) pp. 14500-14505. DOI: https://doi.org/10.1021/acs.inorgchem.2c01587
Documents & Media
Details
- Authors
- Wang, Bing; Zhuang, Yichao; Tu, Danyu; Shen, Liang; Zhang, Zheng-Feng; Su, Ming-Der; Li, Yan; Wu, Di; Roesky, Herbert W.
- Abstract
- Herein we report that the reaction of the low-valent aluminum(I) species [Cp*Al]4 (Cp* = pentamethylcyclopentadienyl) with CO2 exhibits complete cleavages of the C═O bonds. The deoxygenating reduction reaction of [Cp*Al]4 with CO2 at 120 °C afforded [(Cp*)3Al3O2C(CO)]2 (1), which featured two stacked (Al3O2C)2 units and two C═C═O ketene moieties. Moreover, the isoelectronic analogues of diimine and isothiocyanate with CO2 were also investigated, and the reactions of [Cp*Al]4 with Dipp*-N═C═N-Dipp* and Dipp-C═N═S [Dipp* = 2,6-bis(diphenylmethyl)-4-tert-butylphenyl; Dipp = 2,6-diisopropylphenyl] afforded dialuminylimine (2) and tetrameric [Cp*AlS]4 (3), respectively.
- Issue Date
- 2022
- Journal
- Inorganic Chemistry
- Organization
- Institut für Anorganische Chemie
- ISSN
- 0020-1669
- eISSN
- 1520-510X
- Language
- English
