Linker permethylation as a means to foster valence tautomerism and thwart dimerization in ferrocenyl-triarylmethylium cations
2023 | journal article. A publication with affiliation to the University of Göttingen.
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Linker permethylation as a means to foster valence tautomerism and thwart dimerization in ferrocenyl-triarylmethylium cations
Nau, M.; Casper, L. A.; Haug, G.; Linseis, M.; Demeshko, S. & Winter, R. F. (2023)
Dalton Transactions, 52(15) pp. 4674-4677. DOI: https://doi.org/10.1039/D3DT00857F
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Details
- Authors
- Nau, Moritz; Casper, Larissa A.; Haug, Gernot; Linseis, Michael; Demeshko, Serhiy; Winter, Rainer F.
- Abstract
- Permethylation of the phenylene linker in a cationic ferrocenyl-phenylthioxanthylium dyad increases the amount of the diradical ferrocenium thioxanthyl radical valence tautomer and aids in supressing its dimerization.
Permethylation of the phenylene linker in a cationic ferrocenyl-phenylthioxanthylium dyad increases the amount of the diradical ferrocenium thioxanthyl radical valence tautomer and aids in supressing dimerization of the latter and of the one-electron reduced neutral radical. - Issue Date
- 2023
- Journal
- Dalton Transactions
- ISSN
- 1477-9226
- eISSN
- 1477-9234
- Language
- English
- Sponsor
- Studienstiftung des Deutschen Volkes https://doi.org/10.13039/501100004350
Deutsche Forschungsgemeinschaft https://doi.org/10.13039/501100001659
