Hyperthermal velocity distributions of recombinatively-desorbing oxygen from Ag(111)

2023 | journal article. A publication with affiliation to the University of Göttingen.

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​Hyperthermal velocity distributions of recombinatively-desorbing oxygen from Ag(111)​
Dorst, A. C. ; Dissanayake, R. E. A.; Schauermann, D.; Knies, S.; Wodtke, A. M.; Killelea, D. R. & Schäfer, T.​ (2023) 
Frontiers in Chemistry11 art. 1248456​.​ DOI: https://doi.org/10.3389/fchem.2023.1248456 

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Dorst, Arved C. ; Dissanayake, Rasika E. A.; Schauermann, Daniel; Knies, Sofie; Wodtke, Alec M.; Killelea, Daniel R.; Schäfer, Tim
Abstract
This study presents velocity-resolved desorption experiments of recombinatively-desorbing oxygen from Ag (111). We combine molecular beam techniques, ion imaging, and temperature-programmed desorption to obtain translational energy distributions of desorbing O 2 . Molecular beams of NO 2 are used to prepare a p (4 × 4)-O adlayer on the silver crystal. The translational energy distributions of O 2 are shifted towards hyperthermal energies indicating desorption from an intermediate activated molecular chemisorption state.
Issue Date
2023
Journal
Frontiers in Chemistry 
eISSN
2296-2646

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