Photocatalytic Functionalization of Heptacyclo[6.6.0.0 2,6 .0 3,13 .0 4,11 .0 5,9 .0 10,14 ]Tetradecane
2023 | journal article. A publication with affiliation to the University of Göttingen.
Jump to: Cite & Linked | Documents & Media | Details | Version history
Cite this publication
Photocatalytic Functionalization of Heptacyclo[6.6.0.0 2,6 .0 3,13 .0 4,11 .0 5,9 .0 10,14 ]Tetradecane
Recort‐Fornals, M.; Marset, X.; Simon, M.; Golz, C.; Ramón, D. J. & Alcarazo, M. (2023)
Advanced Synthesis & Catalysis, art. adsc.202301323. DOI: https://doi.org/10.1002/adsc.202301323
Documents & Media
Details
- Authors
- Recort‐Fornals, Martí; Marset, Xavier; Simon, Martin; Golz, Christopher; Ramón, Diego J.; Alcarazo, Manuel
- Abstract
- Abstract The regioselective functionalization of heptacyclo[6.6.0.0 2,6 .0 3,13 .0 4,11 .0 5,9 .0 10,14 ]tetradecane (HCTD) under photocatalytic conditions is described. The protocols developed share an initial photo‐triggered hydrogen atom abstraction that regioselectively generates the necessary HCTD‐radical preferentially at position 1‐, they employ no excess of the precious cage carbocycle, and enable the straightforward access to a broad variety of 1‐(alkyl, aryl, or sulfinyl) HCTDs in moderate but still synthetically useful yields. The scope and limitations of each transformation are also discussed.
- Issue Date
- 2023
- Journal
- Advanced Synthesis & Catalysis
- ISSN
- 1615-4150
- eISSN
- 1615-4169
- Language
- English
- Sponsor
- Generalitat Valenciana https://doi.org/10.13039/501100003359
