Preparation and Structural Characterization of Molecular Al-O-Sn(II) and Al-O-Sn(IV) Compounds
2009 | journal article. A publication with affiliation to the University of Göttingen.
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Preparation and Structural Characterization of Molecular Al-O-Sn(II) and Al-O-Sn(IV) Compounds
Nembenna, S.; Singh, S.; Jana, A.; Roesky, H. W.; Yang, Y.; Ye, H. & Ott, H. et al. (2009)
Inorganic Chemistry, 48(5) pp. 2273-2276. DOI: https://doi.org/10.1021/ic802151c
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Details
- Authors
- Nembenna, Sharanappa; Singh, Sanjay; Jana, Anukul; Roesky, Herbert W.; Yang, Y.; Ye, Hongqi; Ott, Holger; Stalke, Dietmar
- Abstract
- Reaction of the organoaluminum hydroxide LAl(Me)OH (1) with different stoichiometric ratios of the homoleptic Sn(II) amide, Sn[N(SiMe(3))(2)](2), produced the bimetallic and trimetallic oxygen bridged aluminum-tin compounds LAl(Me)(mu-O)Sn[N(SiMe(3))(2)] (2) and [LAl(Me)(mu-O)](2)Sn (3), respectively. The former compound exhibits an Al-O-Sn(II)-N core and the latter an Al-O-Sn(II)-O-Al skeleton. In addition, we obtained the [LAl(Me)(mu-O)SnPh(3)] (5) with Al-O-Sn(IV) core by the reaction of [L(Me)Al-O-Mg(THF)(2)N(SiMe(3))(2)] (4) with Ph(3)SnOH in a 1:1 molar ratio.
- Issue Date
- 2009
- Status
- published
- Publisher
- Amer Chemical Soc
- Journal
- Inorganic Chemistry
- ISSN
- 0020-1669
- Sponsor
- Deutsche Forschungsgemeinschaft
