N-Heterocyclic Carbene Adducts of Aluminium Triiodide
2009 | journal article. A publication with affiliation to the University of Göttingen.
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N-Heterocyclic Carbene Adducts of Aluminium Triiodide
Ghadwal, R. S.; Roesky, H. W.; Herbst-Irmer, R. & Jones, P. G. (2009)
Zeitschrift für anorganische und allgemeine Chemie, 635(3) pp. 431-433. DOI: https://doi.org/10.1002/zaac.200801350
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Details
- Authors
- Ghadwal, Rajendra S.; Roesky, Herbert W.; Herbst-Irmer, Regine; Jones, Peter G.
- Abstract
- N-Heterocyclic carbene adducts of aluminium triiodide, 1Mes.AlI(3) (1) and IPr-AlI(3) (2) (lMes = 1.3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene and IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene) are reported. These adducts are available by the reaction of Aluminium triiodide with the corresponding N-heterocyclic carbene. Compounds 1 and 2 are soluble in hydrocarbon solvents, stable in inert atmosphere, and have been characterised by elemental analysis, NMR spectroscopy and single-crystal X-ray diffraction studies.
- Issue Date
- 2009
- Status
- published
- Publisher
- Wiley-v C H Verlag Gmbh
- Journal
- Zeitschrift für anorganische und allgemeine Chemie
- ISSN
- 0044-2313
- Sponsor
- Deutsche Forschungsgemeinschaft
