One Pot Synthesis of Disilatricycloheptene Analogue and Jutzi's Disilene
2010 | journal article. A publication with affiliation to the University of Göttingen.
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One Pot Synthesis of Disilatricycloheptene Analogue and Jutzi's Disilene
Khan, S.; Sen, S. S.; Roesky, H. W.; Kratzert, D.; Michel, R. & Stalke, D. (2010)
Inorganic Chemistry, 49(20) pp. 9689-9693. DOI: https://doi.org/10.1021/ic101552r
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Details
- Authors
- Khan, Shabana; Sen, Sakya S.; Roesky, Herbert W.; Kratzert, Daniel; Michel, Reent; Stalke, Dietmar
- Abstract
- The reaction of LiN(TMS)(2) (TMS = Me(3)Si) with dichlorosilane (Me(5)C(5))SiHCl(2) (1) in a molar ratio of 3:2 at ambient temperature leads to the formation of the disilatricycloheptene analogue (2). Compound 2 consists of three (three-, four-, and five-membered) fused rings that together form a six-membered heterocyclic ring. However, the reaction of 1 with KN(TMS)(2) affords the formation of disilene of composition E-[(TMS)(2)N](eta(1)-Me(5)C(5))Si=Si(eta(1)-Me(5)C(5))[N(TMS)(2)] (3) in good yield. This is a convenient and facile route for the synthesis of 3 in a single step and supports the formation of (Me(5)c(5))SiN(TMS)(2) as an intermediate.
- Issue Date
- 2010
- Status
- published
- Publisher
- Amer Chemical Soc
- Journal
- Inorganic Chemistry
- ISSN
- 0020-1669
- Sponsor
- Deutsche Forschungsgemeinschaft; Deutscher Akademischer Austausch Dienst
