A Facile Route to Functionalized N-Heterocyclic Carbenes (NHCs) with NHC Base-Stabilized Dichlorosilylene
2010 | journal article. A publication with affiliation to the University of Göttingen.
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A Facile Route to Functionalized N-Heterocyclic Carbenes (NHCs) with NHC Base-Stabilized Dichlorosilylene
Ghadwal, R. S.; Roesky, H. W.; Granitzka, M. & Stalke, D. (2010)
Journal of the American Chemical Society, 132(29) pp. 10018-10020. DOI: https://doi.org/10.1021/ja104386g
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Details
- Authors
- Ghadwal, Rajendra S.; Roesky, Herbert W.; Granitzka, Markus; Stalke, Dietmar
- Abstract
- Reaction of IPr.SiCl2 (1) [IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene] with 1-azidoadamantane leads to functionalized N-heterocyclic carbene (NHC) 2. Silyl-substituted NHC 2 reacts easily with 1-azidoadamantane to form triazene 3, in which the exocyclic C=N bond is slightly shorter than those of regular NHC-derived triazines. 2 could serve as a promising ligand for transition metals.
- Issue Date
- 2010
- Status
- published
- Publisher
- Amer Chemical Soc
- Journal
- Journal of the American Chemical Society
- ISSN
- 0002-7863
- Sponsor
- Deutsche Forschungsgemeinschaft (DFG)
