Reactivity Studies of a Ge-1-Ge-1 Compound with and without Cleavage of the Ge-Ge Bond
2010 | journal article. A publication with affiliation to the University of Göttingen.
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Reactivity Studies of a Ge-1-Ge-1 Compound with and without Cleavage of the Ge-Ge Bond
Sen, S. S.; Kratzert, D.; Stern, D.; Roesky, H. W. & Stalke, D. (2010)
Inorganic Chemistry, 49(13) pp. 5786-5788. DOI: https://doi.org/10.1021/ic100501e
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Details
- Authors
- Sen, Sakya S.; Kratzert, Daniel; Stern, Daniel; Roesky, Herbert W.; Stalke, Dietmar
- Abstract
- This Communication describes two strikingly different reactivities of a digermylene [{PhC(NtBu)(2)}(2)Ge-2] (1) featuring a Ge-1-Ge-1 single bond. In the reaction with azobenzene, 1 affords the oxidative addition product LGeN(Ph)N(Ph)GeL [2; L = PhC(NtBu)(2)], with simultaneous cleavage of the Ge-Ge bond, whereas treatment of 1 with Fe-2(CO)(9) yields the Lewis acid-base adduct LGe[Fe(CO)(4)]Ge[(Fe(CO)(4)]L (3). Both compounds were characterized by single-crystal X-ray diffraction, NMR spectroscopy, electrospray ionization mass spectrometry, and elemental analysis.
- Issue Date
- 2010
- Status
- published
- Publisher
- Amer Chemical Soc
- Journal
- Inorganic Chemistry
- ISSN
- 0020-1669
- Sponsor
- Deutsche Forschungsgemeinschaft
