One-Pot Synthesis of a New Magnetically Coupled Heterometallic Cu2Mn2 [2 x 2] Molecular Grid
2010 | journal article. A publication with affiliation to the University of Göttingen.
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One-Pot Synthesis of a New Magnetically Coupled Heterometallic Cu2Mn2 [2 x 2] Molecular Grid
Moroz, Y. S.; Szyrwiel, L.; Demeshko, S.; Kozlowski, H.; Meyer, F. & Fritsky, I. O. (2010)
Inorganic Chemistry, 49(11) pp. 4750-4752. DOI: https://doi.org/10.1021/ic100555s
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Details
- Authors
- Moroz, Yurii. S.; Szyrwiel, Lukasz; Demeshko, Serhiy; Kozlowski, Henryk; Meyer, Franc; Fritsky, Igor O.
- Abstract
- The heterometallic [2 x 2] grid-type complex [Cu2Mn2(pop)(4)(OAc)(4)]center dot 7H(2)O (1) has been selectively synthesized in a targeted one-pot reaction. Single-crystal X-ray analysis shows the expected structure with identical metal ions located at diagonal vertices of the grid. Magnetochemical studies reveal that 1 has a ferrimagnetic spin ground state with some admixture of low-lying excited states.
- Issue Date
- 2010
- Status
- published
- Publisher
- Amer Chemical Soc
- Journal
- Inorganic Chemistry
- ISSN
- 0020-1669
- Sponsor
- DFG [SFB 602]
