Heavier Alkaline Earth Metal Borohydride Complexes Stabilized by beta-Diketiminate Ligand
2010 | journal article. A publication with affiliation to the University of Göttingen.
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Heavier Alkaline Earth Metal Borohydride Complexes Stabilized by beta-Diketiminate Ligand
Sarish, S. P.; Jana, A.; Roesky, H. W.; Schulz, T. G.; John, M. & Stalke, D. (2010)
Inorganic Chemistry, 49(8) pp. 3816-3820. DOI: https://doi.org/10.1021/ic902338r
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Details
- Authors
- Sarish, Sankaranarayana Pillai; Jana, Anukul; Roesky, Herbert W.; Schulz, Thomas G.; John, Michael; Stalke, Dietmar
- Abstract
- The reaction of KB[sec-Bu](3)H with calcium iodide [LCa(mu-I) center dot thf](2)] (1) and strontium iodide [LSr(mu-I) center dot thf](2) (2) yields calcium trisec-butylborohydride LCaB(sec-Bu)(3)H center dot thf (3) and strontium trisec-butylborohydride LSrB(sec-Bu)(3)H center dot thf (4) (L=CH(CMe2,6-tPr(2)C(6)H(3)N)(2)), respectively. Compounds 2, 3, and 4 were characterized by multinuclear NMR spectroscopy, mass spectrometry, elemental analysis, and single crystal X-ray analysis, whereas 1 was characterized without X-ray structural analysis. Compounds 3 and 4 are monomeric in the solid state with a hydride ligation between the metal and boron centers.
- Issue Date
- 2010
- Status
- published
- Publisher
- Amer Chemical Soc
- Journal
- Inorganic Chemistry
- ISSN
- 1520-510X; 0020-1669
- Sponsor
- Deutsche Forschungsgemeinschaft
