Two-step spin crossover in the mononuclear iron(II) complex [Fe-II(L)(2)(NCS)(2)] (L=2,5-di-(2-pyridyl)-1,3,4-thiadiazole)
2010 | journal article. A publication with affiliation to the University of Göttingen.
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Two-step spin crossover in the mononuclear iron(II) complex [Fe-II(L)(2)(NCS)(2)] (L=2,5-di-(2-pyridyl)-1,3,4-thiadiazole)
Klingele, J.; Kaase, D.; Klingele, M. H.; Lach, J. & Demeshko, S. (2010)
Dalton Transactions, 39(7) pp. 1689-1691. DOI: https://doi.org/10.1039/b924223f
Documents & Media
Details
- Authors
- Klingele, Julia; Kaase, Dominik; Klingele, Marco H.; Lach, Jochen; Demeshko, Serhiy
- Abstract
- The first iron(II) complex of 2,5-di-(2-pyridyl)-1,3,4-thiadiazole (L), namely [Fe-II(L)(2)(NCS)(2)], has been synthesised and studied by magnetic susceptibility measurements, Mossbauer spectroscopy and X-ray diffraction. It has been found to undergo thermally-induced spin crossover featuring two well-separated, abrupt steps at T-1/2(1) = 167 K and T-1/2(2) = 112 K.
- Issue Date
- 2010
- Status
- published
- Publisher
- Royal Soc Chemistry
- Journal
- Dalton Transactions
- ISSN
- 1477-9234; 1477-9226
