Germanium(II) hydride mediated reduction of carbon dioxide to formic acid and methanol with ammonia borane as the hydrogen source
2010 | journal article. A publication with affiliation to the University of Göttingen.
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Germanium(II) hydride mediated reduction of carbon dioxide to formic acid and methanol with ammonia borane as the hydrogen source
Jana, A.; Tavcar, G.; Roesky, H. W. & John, M. (2010)
Dalton Transactions, 39(40) pp. 9487-9489. DOI: https://doi.org/10.1039/c0dt00921k
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Details
- Authors
- Jana, Anukul; Tavcar, Gasper; Roesky, Herbert W.; John, Michael
- Abstract
- LGeOC(O)H (3) (L = CH{(CMe)(2,6-iPr(2)C(6)H(3)N)}(2)), from the straightforward conversion of LGeH (2) with CO2, reacts with LiH2NBH3 giving 2 and LiOC(O)H (4), while the corresponding reaction of 3 with H3NBH3 after aqueous workup releases 2 and CH3OH (5). This opens the possibility to use hydride 2 as a mediator in the reduction of carbon dioxide to formic acid and methanol.
- Issue Date
- 2010
- Status
- published
- Publisher
- Royal Soc Chemistry
- Journal
- Dalton Transactions
- ISSN
- 1477-9226
- Sponsor
- Deutsche Forschungsgemeinschaft; Alexander von Humboldt Stiftung
