Syntheses and structures of new organoaluminum fluorides
2000 | journal article. A publication with affiliation to the University of Göttingen.
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- Authors
- Hatop, H.; Roesky, H. W.; Labahn, T.; Fischer, A.; Schmidt, H. G.; Noltemeyer, M.
- Abstract
- This paper reports the synthesis of (Cp2ZrMe)(mu-F)[(Me3Si)(3)CAlF2] (1), [(Cp2Zr)(mu-F)(2)[(Me3Si)(3)CAlF]](2)O (2), and [Na(Me3Si)(3)CAlF3(THF)(])4 (3). 1 was prepared by the reaction of [(M(3)eSi)(3)CAlF2](3) with Cp2ZrMe2 and Me3SnF. Compound 1 reacts with THF to form 2. The reaction of (Me3Si)(3)CAlMe2(THF) with Me3SnF and NaCl affords 3. The molecular structures of compounds 1-3 have been determined by single-crystal X-ray structural analysis.
- Issue Date
- 2000
- Status
- published
- Publisher
- Amer Chemical Soc
- Journal
- Organometallics
- ISSN
- 0276-7333
