Effect of mechanically induced modification on TiH2 thermal stability

2011 | conference paper. A publication with affiliation to the University of Göttingen.

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​Effect of mechanically induced modification on TiH2 thermal stability​
Morozova, O. S.; Khomenko, T. I.; Borchers, C.   & Leonov, A. V.​ (2011)
Journal of Alloys and Compounds509 pp. S754​-S758. ​12th International Symposium on Metal-Hydrogen Systems, Fundamentals and Applications (MH2010)​, Moscow, Russia.
Lausanne​: Elsevier Science Sa. DOI: https://doi.org/10.1016/j.jallcom.2011.01.048 

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Authors
Morozova, Olga S.; Khomenko, T. I.; Borchers, Christine ; Leonov, Alexander V.
Abstract
Interrupted thermal desorption and X-ray diffraction techniques were used to study the effect of graphite and boron additives on non-equilibrium decomposition of mechanically activated commercial TiH2. The phase transformation sequence is described as a number of consecutive reactions corresponding to desorption peaks. The process is compared to non-equilibrium decomposition of commercial TiH2. The mechanical pre-treatment with additives significantly eases and accelerates decomposition of TiH2 to alpha Ti(H), but hinders the stage of alpha Ti( H) -> alpha Ti transformation. Only a small portion of pure alpha Ti was detected for as-milled TiH2 and TiH2/B powders after the final TPD. No alpha Ti was formed in the case of as-milled TiH2/C. (C) 2011 Elsevier B.V. All rights reserved.
Issue Date
2011
Publisher
Elsevier Science Sa
Journal
Journal of Alloys and Compounds 
Organization
Institut für Materialphysik 
Conference
12th International Symposium on Metal-Hydrogen Systems, Fundamentals and Applications (MH2010)
Conference Place
Moscow, Russia
Event start
2010-07-19
Event end
2010-07-23
ISSN
0925-8388

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