Effect of mechanically induced modification on TiH2 thermal stability
2011 | conference paper. A publication with affiliation to the University of Göttingen.
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Effect of mechanically induced modification on TiH2 thermal stability
Morozova, O. S.; Khomenko, T. I.; Borchers, C. & Leonov, A. V. (2011)
Journal of Alloys and Compounds, 509 pp. S754-S758. 12th International Symposium on Metal-Hydrogen Systems, Fundamentals and Applications (MH2010), Moscow, Russia.
Lausanne: Elsevier Science Sa. DOI: https://doi.org/10.1016/j.jallcom.2011.01.048
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- Authors
- Morozova, Olga S.; Khomenko, T. I.; Borchers, Christine ; Leonov, Alexander V.
- Abstract
- Interrupted thermal desorption and X-ray diffraction techniques were used to study the effect of graphite and boron additives on non-equilibrium decomposition of mechanically activated commercial TiH2. The phase transformation sequence is described as a number of consecutive reactions corresponding to desorption peaks. The process is compared to non-equilibrium decomposition of commercial TiH2. The mechanical pre-treatment with additives significantly eases and accelerates decomposition of TiH2 to alpha Ti(H), but hinders the stage of alpha Ti( H) -> alpha Ti transformation. Only a small portion of pure alpha Ti was detected for as-milled TiH2 and TiH2/B powders after the final TPD. No alpha Ti was formed in the case of as-milled TiH2/C. (C) 2011 Elsevier B.V. All rights reserved.
- Issue Date
- 2011
- Publisher
- Elsevier Science Sa
- Journal
- Journal of Alloys and Compounds
- Organization
- Institut für Materialphysik
- Conference
- 12th International Symposium on Metal-Hydrogen Systems, Fundamentals and Applications (MH2010)
- Conference Place
- Moscow, Russia
- Event start
- 2010-07-19
- Event end
- 2010-07-23
- ISSN
- 0925-8388