Lithium Complex of an Abnormal Carbene

2011 | journal article. A publication with affiliation to the University of Göttingen.

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​Lithium Complex of an Abnormal Carbene​
Jana, A.; Azhakar, R.; Tavcar, G.; Roesky, H. W.; Objartel, I. & Stalke, D.​ (2011) 
European Journal of Inorganic Chemistry,(25) pp. 3686​-3689​.​ DOI: https://doi.org/10.1002/ejic.201100574 

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Authors
Jana, Anukul; Azhakar, Ramachandran; Tavcar, Gasper; Roesky, Herbert W.; Objartel, Ina; Stalke, Dietmar
Abstract
A lithium complex of an abnormal carbene with the composition [H3BC{{N(2,6-iPr(2)C(6)H(3))}(2)CHCLi(THF)(3)}] was synthesized by the lithiation reaction of the N-heterocyclic carbene borane adduct {IPr center dot BH3, IPr = [C{[N(2,6-iPr(2)C(6)H(3))]CH}(2)] (1)} with nBuLi. The lithiated species was proven by NMR spectroscopy and unambiguously established by single-crystal X-ray structural analysis.
Issue Date
2011
Status
published
Publisher
Wiley-v C H Verlag Gmbh
Journal
European Journal of Inorganic Chemistry 
ISSN
1434-1948

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