Bridged dinucleating N-heterocyclic carbene ligands and their double helical mercury(II) complexes

Abstract

A series of six 3,6-bis(imidazolium-3-yl)pyridazine derivatives with different imidazole-N substituents have been synthesized and isolated as the salts [H2L]Cl-2 (1a)-(6a) and [H2L](PF6)(2) (1b)-(6b). Solid state structures have been determined crystallographically for eleven out of the twelve compounds, revealing diverse hydrogen bonding patterns that involve the imidazolium-(CH)-H-2 units and the anions. N-heterocyclic carbene (NHC) mercury(II) complexes [Hg2L2](PF6)(4) (7)A9) are readily formed in good yields from ligand precursors [H2L](PF6)(2) and Hg(OAc)(2), as long as imidazole-N substituents are not too bulky. X-ray crystallography reveals double helical bimetallic arrangements for the stable [Hg2L2](4+) cations. Ligand scrambling in [Hg2L2](4+) occurs only in the presence of free carbene precursor, presumably via an associative mechanism. (c) 2006 Elsevier B.V. All rights reserved.