Syntheses of Group 7 Metal Carbonyl Complexes with a Stable N-Heterocyclic Chlorosilylene
2011 | journal article. A publication with affiliation to the University of Göttingen.
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Syntheses of Group 7 Metal Carbonyl Complexes with a Stable N-Heterocyclic Chlorosilylene
Azhakar, R.; Sarish, S. P.; Roesky, H. W.; Hey, J. & Stalke, D. (2011)
Inorganic Chemistry, 50(11) pp. 5039-5043. DOI: https://doi.org/10.1021/ic2003035
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Details
- Authors
- Azhakar, Ramachandran; Sarish, Sankaranarayana Pillai; Roesky, Herbert W.; Hey, Jakob; Stalke, Dietmar
- Abstract
- Two structurally characterized manganese [L2Mn(CO)(4)](+)[Mn(CO)(5)](-) (1) and rhenium [L3Re(CO)(3)](+)[ReCO)(5)](-) (2) silyiene complexes were prepared in one pot syntheses by reacting 1 equivalent of Mn-2(CO)(10) with 2 equivalents of stable N-heterocyclic chlorosilylene L {L = PhC(NtBu)(2) SiC1} and 1 equivalent of Re-2(CO)(10) with 3 equivalents of L in toluene at room temperature. Both complexes 1 and 2 were characterized by single-crystal X-ray structural analysis, NMR and IR spectroscopy, EI-MS spectrometry, and elemental analysis.
- Issue Date
- 2011
- Status
- published
- Publisher
- Amer Chemical Soc
- Journal
- Inorganic Chemistry
- ISSN
- 0020-1669
