Synthesis of a Lewis Base Stabilized Dimer of N-Substituted Hydrosila Hydrazone and a Silaaziridine
2011 | journal article. A publication with affiliation to the University of Göttingen.
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Synthesis of a Lewis Base Stabilized Dimer of N-Substituted Hydrosila Hydrazone and a Silaaziridine
Sarish, S. P.; Jana, A.; Roesky, H. W.; Samuel, P. P.; Andrade, C. E. A.; Dittrich, B. & Schulzke, C. (2011)
Organometallics, 30(4) pp. 912-916. DOI: https://doi.org/10.1021/om101066w
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Details
- Authors
- Sarish, Sankaranarayana Pillai; Jana, Anukul; Roesky, Herbert W.; Samuel, Prinson P.; Andrade, Carlos Enrique Abad; Dittrich, Birger; Schulzke, Carola
- Abstract
- The dehydrohalogenation of a silicon(IV)-substituted diphenyl hydrazone derivative leads to a dimer of a N-substituted hydrosila hydrazone, which consists of a four-membered Si2N2 core and a hydrogen attached to each of the silicon atoms instead of giving a substituted hydrosilaneimine. The compound is obviously formed by dimerization of hydrosilaneimine. Moreover there are no straightforward synthetic methods known for the synthesis of silaaziridine. The preparation of such species would be of special importance for the development of a new field of silicon chemistry. The reaction of chlorosilylene, LSiCl, and PhCH=NPh resulted in a base-stabilized silaaziridine. All compounds were characterized by NMR spectroscopy, mass spectrometry, microanalysis, and X-ray structural analysis.
- Issue Date
- 2011
- Status
- published
- Publisher
- Amer Chemical Soc
- Journal
- Organometallics
- ISSN
- 0276-7333
- Sponsor
- Deutsche Forschungsgemeinschaft
