Pentafluoropyridine as a fluorinating reagent for preparing a hydrocarbon soluble beta-diketiminatolead(II) monofluoride

2011 | journal article. A publication with affiliation to the University of Göttingen.

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​Pentafluoropyridine as a fluorinating reagent for preparing a hydrocarbon soluble beta-diketiminatolead(II) monofluoride​
Jana, A.; Sarish, S. P.; Roesky, H. W.; Leusser, D.; Objartel, I. & Stalke, D.​ (2011) 
Chemical Communications47(19) pp. 5434​-5436​.​ DOI: https://doi.org/10.1039/c1cc11310k 

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Authors
Jana, Anukul; Sarish, Sankaranarayana Pillai; Roesky, Herbert W.; Leusser, Dirk; Objartel, Ina; Stalke, Dietmar
Abstract
A well-designed method for the preparation of a beta-diketiminato lead(II) monofluoride has been developed using LPbNMe(2) (L = [CH{C(Me)(2,6-iPr(2)C(6)H(3)N)}(2)]) and pentafluoropyridine (C(5)F(5)N). The resulting LPbF was used for the synthesis of amidinatosilicon(II) monofluoride. Moreover the activation of a ketone was observed when the LPbF was treated with PhCOCF(3).
Issue Date
2011
Status
published
Publisher
Royal Soc Chemistry
Journal
Chemical Communications 
ISSN
1359-7345
Sponsor
Deutsche Forschungsgemeinschaft; DNRF

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