Synthesis of the titanium compound [(MeC5H4)TiCl(mu-NSiMe3)](2) with migration of a SiMe3 group and preparation of Cp2ZrCl(eta(2)-NHNCHSiMe3}
2001 | journal article. A publication with affiliation to the University of Göttingen.
Jump to: Cite & Linked | Documents & Media | Details | Version history
Cite this publication
Synthesis of the titanium compound [(MeC5H4)TiCl(mu-NSiMe3)](2) with migration of a SiMe3 group and preparation of Cp2ZrCl(eta(2)-NHNCHSiMe3}
Bai, G. C.; Roesky, H. W.; Hao, H. J.; Noltemeyer, M. & Schmidt, H. G. (2001)
Inorganic Chemistry, 40(10) pp. 2424-+. DOI: https://doi.org/10.1021/ic010007x
Documents & Media
Details
- Authors
- Bai, G. C.; Roesky, H. W.; Hao, H. J.; Noltemeyer, M.; Schmidt, H. G.
- Abstract
- Reaction of(MeC5H4)TiCl3 with Me3SiCLiN2 gave the imido-bridged dinuclear titanium complex [(MeC5H4)TiCl(mu -NSiMe3)](2) (1; below left) with migration of a SiMe3 group. The reaction of Cp-2-ZrHCl with Me3SiCHN2 yielded an eta (2)-N-2-zirconium diazoalkane complex Cp2ZrCl(eta (2)-NHNCH-SiMe3) (2; below right). [GRAPHICS]
- Issue Date
- 2001
- Status
- published
- Publisher
- Amer Chemical Soc
- Journal
- Inorganic Chemistry
- ISSN
- 0020-1669
