Organotitanoxanes [C5Me5TiMe2](2)(mu-O)) and [(C5Me5)(4)Ti4Me2](mu-O)(5): Synthesis and crystal structures
2001 | journal article. A publication with affiliation to the University of Göttingen.
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Organotitanoxanes [C5Me5TiMe2](2)(mu-O)) and [(C5Me5)(4)Ti4Me2](mu-O)(5): Synthesis and crystal structures
Varkey, S. P.; Schormann, M.; Pape, T.; Roesky, H. W.; Noltemeyer, M.; Herbst-Irmer, R. & Schmidt, H. G. (2001)
Inorganic Chemistry, 40(10) pp. 2427-+. DOI: https://doi.org/10.1021/ic0013072
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Details
- Authors
- Varkey, S. P.; Schormann, M.; Pape, T.; Roesky, H. W.; Noltemeyer, M.; Herbst-Irmer, R.; Schmidt, H. G.
- Abstract
- Hydrolytic studies on C5Me5TiCl3 and C5Me5TiMe3 resulted in the isolation of [(C5Me5)(4)Ti4Cl2](mu -O)(5) (2a) and [C5Me5TiMe2](2)(mu -O) (1). Compound 2a further reacted with Me3SnF to yield [(CsMe5)(4)Ti4F2](mu -O)(5) (2b). Furthermore, the reactivity of 2b toward AlMe3 has been investigated and results in the formation of [(C5Me5)(4)Ti4Me2](mu -O)(5) (2c). Crystal structures of I and 2c have been established.
- Issue Date
- 2001
- Status
- published
- Publisher
- Amer Chemical Soc
- Journal
- Inorganic Chemistry
- ISSN
- 0020-1669
