Reactivity Studies of LAlH2 (L = HC(CMeNAr)(2), Ar=2,6-iPr(2)C(6)H(3)) with 2-Aminobenzenethiol, 2-Aminophenol, and 1,4-Dithiane-2,5-diol
2012 | journal article. A publication with affiliation to the University of Göttingen.
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Reactivity Studies of LAlH2 (L = HC(CMeNAr)(2), Ar=2,6-iPr(2)C(6)H(3)) with 2-Aminobenzenethiol, 2-Aminophenol, and 1,4-Dithiane-2,5-diol
Yang, Z.; Hao, P.; Liu, Z.; Ma, X.; Roesky, H. W.; Sun, K. & Li, J. (2012)
Organometallics, 31(17) pp. 6500-6503. DOI: https://doi.org/10.1021/om300577j
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Details
- Authors
- Yang, Zhi; Hao, Pengfei; Liu, Zhihong; Ma, Xiaoli; Roesky, Herbert W.; Sun, Kening; Li, Jiarong
- Abstract
- The reaction of LAlH2 (L = HC(CMeNAr)(2), Ar = 2,6-iPr(2)C(6)H(3)) (1) with 2-aminobenzenethiol, 2-aminophenol, and 1,4-dithiane-2,5-diol resulted in the compounds LAl[(mu-N)(mu-S)(o-C6H4) (2), LAl[(mu-O)(o-C6H4)(NH2)](2) (3), and LAl(mu-O)(2)(p-dithiane) (4), respectively. Compound 2 features an organic-inorganic hybrid containing an NAlSC2 five-membered ring, while compound 3 exhibits a C-O-Al-O-C chain structure. Compound 4 forms a basket-like molecule with the C4S2 unit as the bottom part and O2Al as the handle. Complexes 2, 3, and 4 were characterized by H-1 NMR, elemental analysis, and single-crystal X-ray diffraction studies.
- Issue Date
- 2012
- Status
- published
- Publisher
- Amer Chemical Soc
- Journal
- Organometallics
- ISSN
- 0276-7333
