Donor-acceptor stabilized silaformyl chloride
2012 | journal article. A publication with affiliation to the University of Göttingen.
Jump to: Cite & Linked | Documents & Media | Details | Version history
Cite this publication
Donor-acceptor stabilized silaformyl chloride
Ghadwal, R. S.; Azhakar, R.; Roesky, H. W.; Proepper, K.; Dittrich, B.; Goedecke, C. & Frenking, G. (2012)
Chemical Communications, 48(66) pp. 8186-8188. DOI: https://doi.org/10.1039/c2cc32887a
Documents & Media
Details
- Authors
- Ghadwal, Rajendra S.; Azhakar, Ramachandran; Roesky, Herbert W.; Proepper, Kevin; Dittrich, Birger; Goedecke, Catharina; Frenking, Gernot
- Abstract
- Formyl chloride (H(Cl)C=O) is unstable at room temperature and decomposes to HCl and CO. Silicon analogue of formyl chloride, silaformyl chloride IPr center dot SiH(Cl)=O center dot B(C6F5)(3) (3) (IPr = 1,3-bis(2,6-diisopropyl-phenyl)imidazol-2-ylidene), was stabilized by Lewis donor-acceptor ligands. Compound 3 is not only the first stable acyclic silacarbonyl compound but also the first silacarbonyl halide reported so far.
- Issue Date
- 2012
- Status
- published
- Publisher
- Royal Soc Chemistry
- Journal
- Chemical Communications
- ISSN
- 1359-7345
- Sponsor
- Deutsche Forschungsgemeinschaft; AvH foundation
