Lewis base mediated dismutation of trichlorosilane
2012 | journal article. A publication with affiliation to the University of Göttingen.
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Lewis base mediated dismutation of trichlorosilane
Singh, A. P.; Ghadwal, R. S.; Roesky, H. W.; Holstein, J. J.; Dittrich, B.; Demers, J.-P. & Chevelkov, V. et al. (2012)
Chemical Communications, 48(61) pp. 7574-7576. DOI: https://doi.org/10.1039/c2cc33835a
Documents & Media
Details
- Authors
- Singh, Amit Pratap; Ghadwal, Rajendra S.; Roesky, Herbert W.; Holstein, Julian Jacob; Dittrich, Birger; Demers, Jean-Philippe; Chevelkov, Veniamin; Lange, Adam
- Abstract
- An abnormal N-heterocyclic carbene (aNHC) has been used as a Lewis base to initiate dismutation of trichlorosilane. This report presents the reactivity differences of a normal N-heterocyclic carbene (NHC) versus aNHC with heavier group 14 elements. Three novel compounds (NHC)(2)center dot SiCl2H2 (2), aNHC center dot SiCl2H2 (3), and aNHC center dot GeCl2 (4) have been synthesized and characterized by single crystal X-ray analysis, solid-state NMR and DFT calculations.
- Issue Date
- 2012
- Status
- published
- Publisher
- Royal Soc Chemistry
- Journal
- Chemical Communications
- ISSN
- 1359-7345
