Thionitrosyl- and Selenonitrosyliridium Complexes
2013 | journal article. A publication with affiliation to the University of Göttingen.
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Thionitrosyl- and Selenonitrosyliridium Complexes
Scheibel, M. G.; Klopsch, I.; Wolf, H.; Stollberg, P.; Stalke, D. & Schneider, S. (2013)
European Journal of Inorganic Chemistry, 2013(22-23) pp. 3836-3839. DOI: https://doi.org/10.1002/ejic.201377409
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Details
- Authors
- Scheibel, Markus G.; Klopsch, Isabel; Wolf, Hilke; Stollberg, Peter; Stalke, Dietmar; Schneider, Sven
- Abstract
- The activation of elemental sulfur and selenium with electrophilic iridium nitride [Ir(N){N(CHCHPtBu2)(2)}](+) allowed the synthesis of thionitrosyl- and selenonitrosyliridium complexes. The crystallographic and spectroscopic characterization of this rare series of chalcogenonitrosyl complexes [Ir(NE){N(CHCHPtBu2)(2)}](+) (E = none, O, S, Se) is discussed in the context of bonding models. The experimental results indicate strong Ir-N-E multiple-bond character, in agreement with the previously proposed N-E donor-acceptor interaction as an appropriate description for the heavier chalcogens.
- Issue Date
- 2013
- Status
- published
- Publisher
- Wiley-v C H Verlag Gmbh
- Journal
- European Journal of Inorganic Chemistry
- ISSN
- 1099-0682; 1434-1948
