N-Heterocyclic Carbene-facilated Condensation of 3-Methylphenylboronic Acid to the Boroxine
2013 | journal article. A publication with affiliation to the University of Göttingen.
Jump to: Cite & Linked | Documents & Media | Details | Version history
Cite this publication
N-Heterocyclic Carbene-facilated Condensation of 3-Methylphenylboronic Acid to the Boroxine
Zhang, D.; Li, J.; Dong, X.; Zhou, X.; Yang, Z. & Roesky, H. W. (2013)
Zeitschrift für Naturforschung B, 68(5-6) pp. 453-457. DOI: https://doi.org/10.5560/ZNB.2013-2342
Documents & Media
Details
- Authors
- Zhang, D.; Li, Jie; Dong, Xiao; Zhou, X.; Yang, Zhi; Roesky, Herbert W.
- Abstract
- The adduct of (3-MeC6H4)(3)B3O3 with an N-heterocyclic carbene (NHC = 1,3-diethyl-4,5-dimethylimidazol-2-ylidene) was prepared by reacting 2.5 equiv. of 3-methylphenylboronic acid with 1 equiv. of the NHC. This reaction shows a novel carbene-facilitated condensation of substituted phenylboronic acid monomers. The structure of the compound (3-MeC6H4)(3)B3O3(NHC) (1) has been characterized by H-1 NMR spectroscopy, elemental analysis, and single-crystal X-ray diffraction studies.
- Issue Date
- 2013
- Status
- published
- Publisher
- Walter De Gruyter Gmbh
- Journal
- Zeitschrift für Naturforschung B
- ISSN
- 1865-7117; 0932-0776
