Probing the Hofmeister Effect with Ultrafast Core-Hole Spectroscopy
2014-07-16 | journal article; research paper. A publication with affiliation to the University of Göttingen.
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Probing the Hofmeister Effect with Ultrafast Core-Hole Spectroscopy
Yin, Z.; Rajkovic, I.; Kubicek, K.; Quevedo, W.; Pietzsch, A.; Wernet, P. & Föhlisch, A. et al. (2014)
The Journal of Physical Chemistry. B, Condensed matter, materials, surfaces, interfaces & biophysical, 118(31) pp. 9398-9403. DOI: https://doi.org/10.1021/jp504577a
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Details
- Authors
- Yin, Z.; Rajkovic, Ivan; Kubicek, Katharina; Quevedo, Wilson; Pietzsch, Annette; Wernet, Philippe; Föhlisch, Alexander; Techert, Simone
- Abstract
- In the current work, X-ray emission spectra of aqueous solutions of different inorganic salts within the Hofmeister series are presented. The results reflect the direct interaction of the ions with the water molecules and therefore, reveal general properties of the salt-water interactions. Within the experimental precision a significant effect of the ions on the water structure has been observed but no ordering according to the structure maker/structure breaker concept could be mirrored in the results indicating that the Hofmeister effect if existent may be caused by more complex interactions.
- Issue Date
- 16-July-2014
- Journal
- The Journal of Physical Chemistry. B, Condensed matter, materials, surfaces, interfaces & biophysical
- Project
- SFB 1073: Kontrolle von Energiewandlung auf atomaren Skalen
SFB 1073 | Topical Area C | C02 In situ hochauflösende Untersuchung des aktiven Zustands bei der photo- und elektrochemischen Wasserspaltung - Organization
- Institut für Röntgenphysik
- Working Group
- RG Techert (Structural Dynamics in Chemical Systems)
- ISSN
- 1520-6106
- Language
- English
